The Paleozoic-Mesozoic magmatic-tectonic activities and their geological implications in the Zhangjiakou-Xuanhua district, northern margin of the North China Craton
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摘要:
河北省张家口-宣化地区（张宣地区）位于华北克拉通北缘中段，区内自显生宙以来构造活动频繁，并产出大量岩浆岩和金矿床，是研究华北克拉通北缘岩浆-构造-成矿演化体系的重要对象。本文通过对张宣地区的水泉沟正长岩、响水沟似斑状花岗岩、井儿洼粗安岩-英安岩、象山花岗闪长岩、青羊沟黑云母二长花岗岩和张家口组流纹岩的锆石年龄、Lu-Hf同位素和地球化学组成进行研究，结合前人研究成果，获得区内古生代-中生代岩浆岩的侵位时期主要为海西期（峰值398Ma和373Ma）、印支期（峰值234Ma）和燕山期（峰值143Ma和130Ma）。张宣地区在古生代-中生代经历了古亚洲洋俯冲、华北克拉通破坏及古太平洋俯冲过程。早古生代时期，古亚洲洋向华北克拉通俯冲；到泥盆纪，白乃庙岛弧带和华北克拉通北缘发生弧陆碰撞，张宣地区处于弧陆碰撞后的伸展环境，富集地幔岩浆上涌并经历了地壳的同化混染和分离结晶的共同作用，形成大量碱性岩；二叠纪末期-三叠纪，各微陆块相互碰撞，张宣地区处于碰撞后伸展阶段，地幔岩浆引起加厚下地壳的部分熔融，基性、酸性岩浆混合，导致区内的基性岩与酸性岩共存；侏罗纪-白垩纪时期，华北克拉通发生减薄，形成区内大范围的侵入岩和火山岩。张宣地区产有大量金矿、铅锌矿、银矿及少量铜矿和钼矿，金矿集中产于宣化-崇礼-赤城交界处，而银铅锌多金属矿则成群成带环绕金矿化集中区分布。成矿时间主要为海西期和燕山期，印支期成矿尚未明确，但成矿潜力巨大。根据地质特征和同位素组成，可将张宣地区的金矿床划分为"东坪式"、"小营盘式"和"张全庄式"三类。古生代-中生代各时期岩浆活动对金成矿均有贡献，大部分金矿床与海西期和燕山期岩浆活动联系密切，多期次成矿及成矿叠加是形成张宣地区大量金矿床的重要因素。
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关键词:
- 张家口-宣化地区 /
- 古生代-中生代 /
- 岩浆构造活动 /
- 岩浆-构造-成矿系统 /
- 金矿
Abstract:The Zhangjiakou-Xuanhua area is located in the central part of the northern margin of the North China Craton (NCC). There are many tectonic activities during Phanerozoic,and lots of magmatic rocks and gold deposits were developed in this area,which is an important case to study magmatic-tectonic-metallogenic evolution systems of the northern margin of the NCC. In this study,we present zircon U-Pb ages,Lu-Hf isotope and geochemical compositions of the Shuiquangou syenite,the Xiangshuigou porphyritic granite,the Jingerwa granite,the Xiangshan granodiorite,the Qingyanggou biotite monzogranite and the Zhangjiakou Formation rhyolite. Combineing with previously published results in the Zhangjiakou-Xuanhua area,three periods of magmatic activity have been recognized during the Paleozoic to Mesozoic. They are the Hercynian magmatic activity with peak ages of 398Ma and 373Ma,the Indosinian magmatic activity with peak age of 234Ma and the Yanshanian magmatic activity with peak ages of 143Ma and 130Ma. The Zhangjiakou-Xuanhua area had suffered subduction of the Paleo-Asian Ocean (PAO),destruction of the NCC and subduction of the Paleo-Pacific Ocean (PPO). During the Early Paleozoic,the PAO subducted under the NCC. At Devonian,arc-continental collision occurred between the Bainaimiao arc and the northern margin of the NCC,and the Zhangjiakou-Xuanhua area was in a post-collisional extensional environment. The enriched mantle magma upwelled and suffered crustal assimilation and fractional crystallization,creating lots of alkaline rocks. During the Late Permian to Triassic,the microcontinents collided with each other,and the study area was under post-collision extensional setting. The thickened lower crust was heated by mantle magma,leading to mixing of basic- and acid-magmas,generating the coexistence of mafic and felsic igneous rocks. During the Jurassic to Cretaceous,thinning of the NCC resulted in the widely distributed intrusive and volcanic rocks. Large amounts of Au,Pb-Zn,Ag deposits and several Cu and Mo deposits developed in the Zhangjiakou-Xuanhua area. Gold deposits mostly located in the junction area of Xuanhua,Chongli,Chicheng counties,while Pb-Zn-Ag deposits distributed around the gold mineralization area. Mineralization ages of deposits were concentrated in the Hercynian and Yanshanian,and it is unclear whether mineralization occurred in the Indosinian,but existing great metallogenic potential. Gold deposits in the Zhangjiakou-Xuanhua area could be divided into the "Dongping type",the "Xiaoyingpan type" and the "Zhangquanzhuang type" according to their geological and isotope characteristics. The Paleozoic Mesozoic magmatic activities were contributed to gold mineralization,and most gold deposits had genetic relationships with the Hercynian and Yanshanian magmatic activities. Multi-stage and superimposed mineralization are the essential factors to generate the large amounts of gold deposits in the Zhangjiakou-Xuanhua area.
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图 1
张宣地区大地构造位置(a)及区域地质简图(b)(据甄世民等, 2019①)
Figure 1.
Sketch maps of (a) geotectonic location and (b) tectonic-magmatic framework of the Zhangjiakou-Xuanhua area
图 2
张宣地区地质矿产图(据Zhen et al., 2020)
Figure 2.
Sketch map of geology and ore deposits of the Zhangjiakou-Xuanhua area (modified after Zhen et al., 2020)
图 3
张宣地区岩浆岩野外及镜下照片
Figure 3.
Field photos and microphotographs of magmatic rocks in the Zhangjiakou-Xuanhua area
图 4
张宣地区古生代-中生代岩浆岩锆石CL图像
Figure 4.
Zircon CL images of the Paleozoic-Mesozoic igneous rocks from the Zhangjiakou-Xuanhua area
图 5
张宣地区古生代-中生代岩浆岩锆石U-Pb年龄
Figure 5.
Zircon U-Pb ages of the PaleozoicMesozoic igneous rocks from the Zhangjiakou-Xuanhua area
图 6
张宣地区古生代-中生代岩浆岩球粒陨石标准化稀土元素配分图和原始地幔标准化微量元素蛛网图(标准化值据Sun and McDonough, 1989)
Figure 6.
Chondrite-normalized REE patterns and primitive mantle-normalized element spider diagrams for the Paleozoic-Mesozoic igneous rocks from the Zhangjiakou-Xuanhua area (normalization values after Sun and McDonough, 1989)
图 7
张宣地区古生代-中生代岩浆岩成岩年龄统计图
Figure 7.
Statistical diagram of diagenetic ages for the PaleozoicMesozoic igneous rocks from the Zhangjiakou-Xuanhua area
图 8
张宣地区古生代-中生代岩浆岩Hf同位素分布图
Figure 8.
Scattergrams of Hf isotope compositions for the Paleozoic-Mesozoic igneous rocks from the Zhangjiakou-Xuanhua area
图 9
张宣地区古生代-中生代岩浆岩Sr-Nd同位素分布图
Figure 9.
Scattergrams of Sr-Nd isotope compositions for the Paleozoic-Mesozoic igneous rocks from the Zhangjiakou-Xuanhua area
图 11
张宣地区三叠纪花岗岩埃达克岩判别图解(底图据Defant and Drummond, 1993)
Figure 11.
Discrimination diagrams of adakitic rocks for the Triassic granites from the Zhangjiakou-Xuanhua area (base map after Defant and Drummond, 1993)
图 12
张宣地区晚侏罗世-早白垩世岩浆岩A型花岗岩和高分异花岗岩判别图解(底图据Whalen et al., 1987)
Figure 12.
Discrimination diagrams of A-type and highly-fractionated granites for the Late Jurassic-Early Cretaceous igneous rocks from the Zhangjiakou-Xuanhua area (base map after Whalen et al., 1987)
图 13
张宣地区古生代-中生代岩浆-构造演化模式图
Figure 13.
Model of the Paleozoic-Mesozoic magmatic-tectonic evolution from the Zhangjiakou-Xuanhua area
图 14
张宣地区金矿床H-O-S-Pb-He-Ar同位素组成(a, 底图据Taylor, 1974; c, d, 底图据Zartman and Doe, 1981；e, f, 底图据Mamyrin and Tolstikhin, 1984)
Figure 14.
H-O-S-Pb-He-Ar isotope compositions of gold deposits in the Zhangjiakou-Xuanhua area (a, after Taylor, 1974; c, d, after Zartman and Doe, 1981; e, f, after Mamyrin and Tolstikhin, 1984)
图 15
张宣地区成岩成矿年龄分布图
Figure 15.
Distribution diagram of diagenetic and metallogenic ages from the Zhangjiakou-Xuanhua area
表 1
张宣地区岩浆岩锆石U-Pb年龄
Table 1.
Zircon U-Pb ages of igneous rocks from the Zhangjiakou-Xuanhua area
测点号 
Th/U 同位素比值 年龄(Ma) 
1σ 
1σ 
1σ 
1σ 
1σ 
1σ SQG-1水泉沟正长岩 -1 19 85 0.22 0.0598 0.0028 0.5142 0.0240 0.0639 0.0008 570 104 422 16 399 5 -2 68 238 0.28 0.0561 0.0017 0.4837 0.0151 0.0634 0.0006 440 74 402 10 396 3 -3 7 45 0.15 0.0551 0.0036 0.4560 0.0255 0.0633 0.0012 389 152 382 18 396 7 -4 4 28 0.15 0.0670 0.0049 0.5669 0.0377 0.0637 0.0012 818 150 457 25 399 7 -5 41 329 0.12 0.0569 0.0014 0.4963 0.0112 0.0643 0.0006 461 56 410 8 402 4 -6 2 19 0.11 0.0518 0.0051 0.4489 0.0363 0.0637 0.0014 246 218 377 26 399 8 -7 14 72 0.19 0.0556 0.0027 0.4770 0.0228 0.0637 0.0008 474 106 397 16 398 5 -8 3 29 0.10 0.0513 0.0039 0.4349 0.0318 0.0637 0.0014 224 180 368 23 398 8 -9 31 256 0.12 0.0567 0.0016 0.4933 0.0141 0.0637 0.0006 462 62 408 10 398 4 -10 6 52 0.12 0.0501 0.0029 0.4359 0.0244 0.0630 0.0008 167 133 368 17 394 5 -11 2 14 0.11 0.0646 0.0064 0.5353 0.0426 0.0639 0.0017 742 212 437 28 399 10 -12 45 236 0.19 0.0559 0.0017 0.4748 0.0143 0.0628 0.0008 423 70 395 10 393 5 -13 2 20 0.11 0.0606 0.0064 0.4693 0.0377 0.0616 0.0013 600 233 392 26 385 8 -14 32 217 0.15 0.0560 0.0016 0.4858 0.0145 0.0639 0.0007 423 68 403 10 399 4 -15 35 151 0.23 0.0573 0.0020 0.4944 0.0171 0.0636 0.0007 485 79 409 12 398 4 -16 16 61 0.26 0.0590 0.0031 0.5017 0.0248 0.0634 0.0009 609 121 414 17 396 5 -17 641 1856 0.35 0.0550 0.0010 0.4875 0.0089 0.0650 0.0006 382 37 404 6 406 4 -18 3 19 0.15 0.0776 0.0097 0.6395 0.0646 0.0639 0.0018 1123 258 504 40 399 11 -19 279 595 0.47 0.0601 0.0017 0.5311 0.0145 0.0648 0.0007 585 57 434 10 405 5 -20 28 366 0.08 0.0542 0.0014 0.4783 0.0122 0.0649 0.0008 352 62 398 9 406 5 -21 2541 2715 0.94 0.0550 0.0009 0.4904 0.0089 0.0653 0.0008 395 38 406 6 408 5 -22 15 91 0.17 0.0563 0.0028 0.4844 0.0226 0.0638 0.0011 438 144 402 16 399 7 -23 11 54 0.20 0.0537 0.0030 0.4647 0.0246 0.0646 0.0011 329 134 388 17 404 7 -24 20 108 0.18 0.0569 0.0028 0.4942 0.0222 0.0643 0.0009 461 113 409 15 402 6 -25 26 104 0.25 0.0658 0.0028 0.5670 0.0259 0.0634 0.0015 780 90 457 17 396 9 -26 676 1657 0.41 0.0543 0.0011 0.4783 0.0100 0.0647 0.0007 355 49 398 7 404 4 -27 92 365 0.25 0.0569 0.0014 0.4979 0.0123 0.0643 0.0006 461 56 411 8 402 4 -28 45 623 0.07 0.0560 0.0014 0.4926 0.0141 0.0644 0.0009 427 56 408 10 402 6 XSG-5响水沟似斑状花岗岩 -1 295 430 0.69 0.0528 0.0026 0.2628 0.0129 0.0360 0.0005 317 115 237 10 228 3 -2 204 386 0.53 0.0547 0.0026 0.2726 0.0127 0.0360 0.0005 398 101 245 10 228 3 -3 169 390 0.43 0.0525 0.0028 0.2682 0.0145 0.0371 0.0005 309 119 241 12 235 3 -4 111 218 0.51 0.0632 0.0037 0.3256 0.0200 0.0369 0.0006 722 126 286 15 234 4 -5 167 339 0.49 0.0534 0.0027 0.2759 0.0149 0.0370 0.0005 346 115 247 12 235 3 -6 640 471 1.36 0.0519 0.0026 0.2666 0.0132 0.0370 0.0005 283 117 240 11 234 3 -7 108 252 0.43 0.0559 0.0049 0.2762 0.0237 0.0360 0.0009 456 196 248 19 228 6 -8 81 104 0.77 0.1155 0.0093 0.2880 0.0252 0.0189 0.0005 1888 114 257 20 120 3 -9 121 175 0.69 0.0638 0.0052 0.3109 0.0237 0.0360 0.0006 744 174 275 18 228 4 -10 233 334 0.70 0.0589 0.0037 0.3066 0.0197 0.0373 0.0006 565 137 272 15 236 4 -11 240 353 0.68 0.0544 0.0044 0.2777 0.0200 0.0374 0.0007 387 183 249 16 237 4 -12 90 100 0.90 0.0635 0.0053 0.3005 0.0249 0.0355 0.0009 724 181 267 19 225 6 -13 405 514 0.79 0.0517 0.0024 0.2637 0.0125 0.0365 0.0004 333 105 238 10 231 3 -14 83 213 0.39 0.0599 0.0037 0.3088 0.0177 0.0378 0.0006 598 131 273 14 239 4 -15 214 431 0.50 0.0513 0.0023 0.2493 0.0111 0.0349 0.0004 254 104 226 9 221 3 JEW-01井儿洼粗安岩-英安岩 -1 55 77 0.72 0.0582 0.0151 0.2044 0.0537 0.0259 0.0015 539 494 189 45 165 10 -2 41 96 0.43 0.0723 0.0237 0.1784 0.0384 0.0247 0.0014 994 710 167 33 158 8 -3 250 309 0.81 0.0526 0.0057 0.1881 0.0151 0.0272 0.0008 309 248 175 13 173 5 -4 25 45 0.55 0.0568 0.0202 0.1674 0.0489 0.0245 0.0015 483 637 157 43 156 10 -5 206 341 0.60 0.0523 0.0059 0.1813 0.0146 0.0259 0.0008 298 292 169 13 165 5 -6 60 83 0.72 0.0526 0.0114 0.2002 0.0313 0.0278 0.0012 309 431 185 26 177 7 -7 99 120 0.83 0.0682 0.0177 0.1860 0.0424 0.0258 0.0011 876 558 173 36 164 7 -8 111 164 0.68 0.0800 0.0184 0.1928 0.0318 0.0242 0.0011 1198 469 179 27 154 7 T-PM00-1象山花岗闪长岩 -1 81 100 0.81 0.0586 0.0052 0.1576 0.0123 0.0201 0.0004 550 201 149 11 128 3 -2 118 122 0.96 0.0588 0.0062 0.1542 0.0150 0.0203 0.0004 567 232 146 13 129 3 -3 84 90 0.94 0.0560 0.0056 0.1525 0.0136 0.0210 0.0006 454 222 144 12 134 4 -4 227 184 1.23 0.0642 0.0051 0.1912 0.0155 0.0215 0.0005 746 167 178 13 137 3 -5 180 186 0.97 0.0550 0.0038 0.1631 0.0101 0.0221 0.0004 409 153 153 9 141 2 -6 303 231 1.31 0.1269 0.0093 0.4297 0.0348 0.0231 0.0004 2055 130 363 25 147 3 -7 75 98 0.77 0.0537 0.0051 0.1573 0.0123 0.0220 0.0005 367 219 148 11 140 3 -8 150 202 0.74 0.0495 0.0034 0.1468 0.0087 0.0217 0.0004 172 159 139 8 138 2 -9 123 108 1.13 0.1941 0.0126 0.6754 0.0479 0.0246 0.0007 2777 73 524 29 157 4 -10 70 94 0.74 0.0971 0.0482 0.3237 0.2098 0.0212 0.0005 1569 1076 285 161 135 3 -11 105 154 0.68 0.0529 0.0035 0.1468 0.0084 0.0210 0.0004 324 156 139 7 134 3 -12 56 69 0.81 0.0536 0.0063 0.1509 0.0150 0.0211 0.0006 354 268 143 13 135 4 -14 72 93 0.78 0.0613 0.0058 0.1707 0.0130 0.0215 0.0005 650 204 160 11 137 3 -15 106 142 0.75 0.0974 0.0420 0.3205 0.1562 0.0237 0.0005 1576 894 282 120 151 3 -16 405 287 1.41 0.0489 0.0027 0.1360 0.0070 0.0201 0.0003 146 162 130 6 128 2 -17 139 129 1.08 0.0440 0.0052 0.1414 0.0202 0.0226 0.0005 - - 134 18 144 3 -18 126 154 0.81 0.0561 0.0038 0.1636 0.0107 0.0214 0.0004 454 150 154 9 137 3 -19 100 126 0.79 0.0560 0.0045 0.1605 0.0115 0.0210 0.0004 454 184 151 10 134 3 -20 140 148 0.94 0.0516 0.0041 0.1507 0.0101 0.0214 0.0004 333 185 143 9 137 3 -21 134 145 0.92 0.0511 0.0043 0.1475 0.0113 0.0210 0.0004 256 198 140 10 134 3 -22 113 145 0.78 0.1217 0.0108 0.4382 0.0397 0.0242 0.0006 1983 158 369 28 154 4 -23 104 109 0.95 0.0525 0.0047 0.1502 0.0112 0.0216 0.0004 306 206 142 10 138 3 -24 59 73 0.81 0.0530 0.0070 0.1554 0.0149 0.0233 0.0006 328 278 147 13 149 4 -25 146 177 0.82 0.0652 0.0070 0.2047 0.0225 0.0235 0.0004 783 197 189 19 150 3 -26 341 225 1.52 0.0584 0.0039 0.1806 0.0107 0.0228 0.0003 546 145 169 9 145 2 -27 122 152 0.80 0.0484 0.0041 0.1466 0.0101 0.0227 0.0005 120 185 139 9 145 3 -29 56 71 0.79 0.0570 0.0064 0.1658 0.0156 0.0224 0.0006 500 250 156 14 143 4 -30 72 95 0.76 0.0587 0.0061 0.1700 0.0160 0.0221 0.0009 567 223 159 14 141 6 -32 144 182 0.79 0.0607 0.0051 0.1783 0.0154 0.0216 0.0004 628 182 167 13 137 3 -33 133 152 0.88 0.0511 0.0053 0.1643 0.0143 0.0250 0.0006 256 217 154 12 159 4 -34 192 197 0.97 0.0511 0.0037 0.1547 0.0102 0.0219 0.0004 256 170 146 9 140 2 -35 103 103 1.00 0.0566 0.0055 0.1581 0.0133 0.0209 0.0004 476 212 149 12 133 3 B0169青羊沟黑云母二长花岗岩 -1 404 192 2.10 0.0503 0.0019 0.1402 0.0051 0.0205 0.0002 206 89 133 5 131 2 -2 1100 569 1.93 0.0739 0.0045 0.2105 0.0147 0.0201 0.0002 1039 128 194 12 128 1 -3 311 237 1.31 0.0480 0.0020 0.1320 0.0053 0.0201 0.0002 102 -103 126 5 128 1 -4 392 349 1.12 0.1149 0.0074 0.3631 0.0256 0.0217 0.0003 1880 117 315 19 138 2 -5 602 379 1.59 0.0856 0.0054 0.2551 0.0177 0.0209 0.0003 1329 90 231 14 133 2 -6 552 176 3.13 0.0479 0.0024 0.1254 0.0066 0.0190 0.0002 98 115 120 6 121 1 -7 64 51 1.26 0.0561 0.0038 0.1780 0.0114 0.0232 0.0004 457 150 166 10 148 3 -8 490 241 2.04 0.0500 0.0018 0.1328 0.0047 0.0193 0.0002 198 85 127 4 123 1 -9 412 183 2.24 0.0467 0.0021 0.1283 0.0057 0.0201 0.0002 32 107 123 5 128 1 -10 706 371 1.90 0.0581 0.0028 0.1811 0.0116 0.0217 0.0003 600 101 169 10 138 2 -11 673 430 1.57 0.0502 0.0015 0.1392 0.0038 0.0201 0.0002 211 67 132 3 128 1 -12 1135 647 1.75 0.0551 0.0012 0.1530 0.0036 0.0201 0.0002 417 50 145 3 128 1 -13 475 304 1.56 0.0529 0.0021 0.1632 0.0071 0.0223 0.0003 324 91 153 6 142 2 -14 222 174 1.27 0.1858 0.0107 0.6734 0.0500 0.0238 0.0005 2705 95 523 30 152 3 -15 253 181 1.40 0.0459 0.0022 0.1242 0.0059 0.0197 0.0003 error 119 5 126 2 -16 363 207 1.75 0.0549 0.0028 0.1643 0.0085 0.0217 0.0003 409 108 154 7 138 2 -17 170 172 0.99 0.0553 0.0030 0.1602 0.0084 0.0212 0.0003 433 120 151 7 135 2 -18 60 46 1.30 0.0537 0.0054 0.1447 0.0124 0.0201 0.0005 367 223 137 11 128 3 -19 1046 559 1.87 0.0471 0.0013 0.1408 0.0040 0.0216 0.0002 54 63 134 4 138 1 -20 1316 603 2.18 0.0501 0.0014 0.1395 0.0041 0.0201 0.0002 211 32 133 4 128 1 ZJK-1张家口组流纹岩 -1 51 44 1.17 0.0513 0.0064 0.1434 0.013 0.0214 0.0005 254 263 136 11.6 136 3.4 -2 54 47 1.15 0.0556 0.0069 0.1582 0.0148 0.0224 0.0007 435 284 149 13 143 4.3 -3 71 56 1.27 0.0515 0.0061 0.1481 0.0139 0.0214 0.0005 265 252 140 12.3 136 3.1 -4 46 40 1.16 0.0543 0.007 0.1464 0.014 0.0213 0.0006 389 297 139 12.4 136 3.5 -5 101 52 1.95 0.0533 0.0099 0.1636 0.0228 0.0239 0.0012 343 380 154 19.9 152 7.3 -6 49 49 1.01 0.0733 0.011 0.172 0.0164 0.0188 0.0007 1020 308 161 14.2 120 4.6 -7 41 35 1.18 0.0589 0.0082 0.1654 0.0183 0.0217 0.0006 561 304 155 15.9 138 3.9 -8 64 59 1.08 0.0742 0.0082 0.1933 0.0189 0.0198 0.0006 1048 226 179 16.1 126 3.5 -9 39 34 1.15 0.0633 0.0118 0.1387 0.0104 0.0213 0.0007 720 404 132 9.3 136 4.5 -10 103 62 1.66 0.0535 0.0055 0.1414 0.0115 0.0207 0.0005 350 235 134 10.2 132 3.3 -11 75 58 1.29 0.0597 0.0059 0.1556 0.0113 0.0207 0.0005 591 215 147 9.9 132 3.1 -12 49 41 1.18 0.0591 0.0082 0.1492 0.0118 0.0207 0.0006 569 310 141 10.4 132 3.7 -13 186 105 1.77 0.0492 0.0043 0.138 0.0101 0.0214 0.0004 154 196 131 9 136 2.6 -14 80 50 1.6 0.0497 0.0061 0.1311 0.0124 0.021 0.0005 189 267 125 11.1 134 3 -15 44 37 1.19 0.0576 0.0084 0.1475 0.0143 0.0211 0.0005 522 319 140 12.6 134 3.4 -16 47 42 1.12 0.1049 0.0124 0.2964 0.0318 0.0207 0.0006 1722 218 264 24.9 132 3.7 -17 49 42 1.16 0.0558 0.0078 0.1474 0.0162 0.0212 0.0006 443 315 140 14.4 135 3.6 -18 57 48 1.21 0.0463 0.0057 0.1299 0.0152 0.0209 0.0005 16.8 270 124 13.6 133 3.3 -19 277 381 0.73 0.0514 0.0024 0.1501 0.0068 0.0214 0.0003 257 107 142 6 136 1.8 -20 136 78 1.75 0.0534 0.0056 0.1452 0.0126 0.021 0.0005 343 239 138 11.2 134 2.9 -21 82 53 1.54 0.0868 0.0074 0.2379 0.0157 0.0212 0.0005 1367 165 217 12.8 135 3.4 
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表 2
张宣地区岩浆岩锆石Lu-Hf同位素组成
Table 2.
Zircon Lu-Hf isotope compositions of igneous rocks from the Zhangjiakou-Xuanhua area
测点号 年龄(Ma) 176Yb/177Hf 1σ 176Lu/177Hf 1σ 176Hf/177Hf 1σ εHf(0) εHf(t) tDM (Ma) tDMC (Ma) fLu/Hf SQG-1水泉沟正长岩 -1 399 0.006646 0.00004 0.000328 0.00000 0.281947 0.00002 -29.2 -20.5 1802 2682 -0.99 -2 396 0.024322 0.00030 0.001156 0.00001 0.281946 0.00001 -29.2 -20.8 1844 2700 -0.97 -6 399 0.003355 0.00009 0.000173 0.00001 0.281903 0.00001 -30.7 -22.0 1855 2778 -0.99 -7 398 0.005230 0.00015 0.000272 0.00001 0.281970 0.00002 -28.4 -19.7 1768 2631 -0.99 -16 396 0.019718 0.00018 0.000964 0.00001 0.281944 0.00002 -29.3 -20.9 1837 2702 -0.97 -22 399 0.004203 0.00007 0.000221 0.00000 0.281915 0.00001 -30.3 -21.6 1841 2752 -0.99 -23 404 0.006368 0.00012 0.000331 0.00001 0.281919 0.00002 -30.2 -21.4 1841 2741 -0.99 -24 402 0.008293 0.00023 0.000423 0.00001 0.281879 0.00002 -31.6 -22.9 1900 2833 -0.99 XSG-5响水沟似斑状花岗岩 -1 228 0.013945 0.00004 0.000562 0.00000 0.282179 0.00001 -21.0 -16.1 1496 2278 -0.98 -2 228 0.013978 0.00044 0.000544 0.00001 0.282161 0.00001 -21.6 -16.7 1518 2316 -0.98 -3 235 0.017295 0.00039 0.000690 0.00001 0.282178 0.00001 -21.0 -15.9 1501 2275 -0.98 -4 234 0.016069 0.00014 0.000664 0.00001 0.282172 0.00001 -21.2 -16.2 1509 2290 -0.98 -8 228 0.015461 0.00021 0.000629 0.00001 0.282186 0.00001 -20.7 -15.8 1488 2262 -0.98 -10 228 0.019892 0.00031 0.000759 0.00001 0.282142 0.00001 -22.3 -17.4 1554 2361 -0.98 -14 225 0.039011 0.00033 0.001493 0.00001 0.282266 0.00001 -17.9 -13.2 1409 2092 -0.96 -15 231 0.024712 0.00031 0.000938 0.00001 0.282163 0.00001 -21.5 -16.6 1532 2314 -0.97 JEW-1井儿洼粗安岩-英安岩 -1 165 0.027743 0.00045 0.001019 0.00001 0.282538 0.00005 -8.3 -4.8 1011 1516 -0.97 -2 158 0.048221 0.00018 0.001797 0.00001 0.282607 0.00005 -5.8 -2.6 933 1372 -0.95 -3 173 0.085136 0.00083 0.003179 0.00003 0.282855 0.00006 2.9 6.4 597 811 -0.90 -5 165 0.034647 0.00019 0.001414 0.00001 0.282271 0.00003 -17.7 -14.2 1399 2116 -0.96 -6 177 0.047679 0.00045 0.001664 0.00002 0.282776 0.00004 0.1 3.8 687 977 -0.95 -7 164 0.031591 0.00030 0.001142 0.00001 0.282691 0.00006 -2.9 0.6 798 1173 -0.97 -8 154 0.039777 0.00011 0.001437 0.00000 0.282567 0.00005 -7.2 -4.3 981 1467 -0.96 T-PM00-1象山花岗闪长岩 -4 137 0.023427 0.00021 0.000978 0.00001 0.281980 0.00002 -28.0 -25.1 1787 2776 -0.97 -5 141 0.020044 0.00012 0.000887 0.00001 0.282035 0.00002 -26.1 -23.1 1708 2653 -0.97 -8 138 0.026396 0.00014 0.001152 0.00001 0.282026 0.00002 -26.4 -23.5 1732 2675 -0.97 -10 135 0.023608 0.00011 0.000989 0.00000 0.282033 0.00002 -26.1 -23.2 1715 2661 -0.97 -14 137 0.007391 0.00005 0.000322 0.00000 0.282046 0.00002 -25.7 -22.7 1668 2628 -0.99 -18 137 0.013641 0.00008 0.000618 0.00000 0.282064 0.00002 -25.0 -22.1 1655 2588 -0.98 -20 137 0.190456 0.00031 0.000832 0.00001 0.282012 0.00002 -26.9 -24.0 1737 2706 -0.97 -23 138 0.016664 0.00014 0.000712 0.00001 0.282090 0.00002 -24.1 -21.1 1623 2530 -0.98 -30 141 0.014425 0.00005 0.000639 0.00000 0.282067 0.00002 -24.9 -21.9 1652 2579 -0.98 -29 143 0.009203 0.00002 0.000418 0.00000 0.282051 0.00002 -25.5 -22.4 1664 2612 -0.99 -32 137 0.015310 0.00003 0.000694 0.00000 0.282056 0.00002 -25.3 -22.4 1670 2607 -0.98 -34 140 0.014320 0.00021 0.000636 0.00001 0.282036 0.00002 -26.0 -23.0 1695 2650 -0.98 B-0169青羊沟黑云母二长花岗岩 -01 131 0.044784 0.00011 0.001472 0.00001 0.282051 0.00002 -25.5 -22.8 1712 2627 -0.96 -04 138 0.068482 0.00045 0.002140 0.00001 0.282122 0.00001 -23.0 -20.3 1641 2470 -0.94 -06 121 0.049489 0.00023 0.001647 0.00001 0.282047 0.00002 -25.6 -22.9 1726 2636 -0.95 -07 148 0.060908 0.00008 0.002003 0.00000 0.282063 0.00002 -25.1 -22.3 1719 2600 -0.94 -09 128 0.068334 0.00046 0.002272 0.00001 0.282099 0.00002 -23.8 -21.1 1680 2522 -0.93 ZJK-1张家口组流纹岩 -3 136 0.024759 0.00022 0.000958 0.00001 0.282270 0.00001 -17.8 -14.9 1384 2133 -0.97 -4 136 0.016421 0.00011 0.000643 0.00001 0.282309 0.00002 -16.4 -13.4 1318 2043 -0.98 -9 136 0.019441 0.00020 0.000768 0.00001 0.282231 0.00001 -19.1 -16.2 1431 2218 -0.98 -11 132 0.029273 0.00024 0.001107 0.00001 0.282242 0.00001 -18.7 -15.9 1429 2198 -0.97 -13 136 0.067141 0.00060 0.002535 0.00002 0.282225 0.00002 -19.3 -16.6 1509 2241 -0.92 -17 135 0.056560 0.00128 0.002176 0.00005 0.282259 0.00002 -18.1 -15.4 1446 2164 -0.93 -20 134 0.015795 0.00016 0.000619 0.00001 0.282264 0.00001 -18.0 -15.1 1380 2146 -0.98
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表 3
张宣地区岩浆岩全岩主量(wt%)、微量(×10-6)元素组成
Table 3.
Whole-rock major (wt%) and trace (×10-6) element compositions of igneous rocks from the Zhangjiakou-Xuanhua area
样品号 SQG-1 SQG-2 SQG-3 XSG-2 XSG-3 XSG-4 XSG-5 T-PM00-38 T-PM00-39 T-PM00-40 T-PM00-41 T-PM00-42 T-PM00-43 岩性 水泉沟正长岩 响水沟似斑状花岗岩 象山花岗闪长岩 SiO2 63.79 63.6 64.79 71.06 71.04 68.45 61.36 68.9 67.86 67.19 71.18 69.26 69.15 TiO2 0.16 0.11 0.12 0.16 0.18 0.18 0.2 0.64 0.79 0.77 0.61 0.63 0.73 Al2O3 19.02 18.8 18.92 15.94 15.94 16.22 20.21 12.5 11.83 12.52 12.06 12.24 12.12 Fe2O3T 1.37 1.34 1.31 1.07 1.12 0.93 1.37 4.51 5.57 5.65 4.1 4.66 4.81 MnO 0.04 0.05 0.08 0.02 0.02 0.03 0.03 0.1 0.12 0.15 0.11 0.14 0.11 MgO 0.12 0.08 0.06 0.26 0.29 0.26 0.33 3.65 3.63 3.72 2.48 3.6 3.72 CaO 1.66 1.61 1.82 1.55 1.6 2.34 2.01 0.57 0.63 0.66 0.49 0.59 0.61 Na2O 6.43 6 7.23 5.08 5.08 3.26 6.89 1.43 1.26 1.49 1.41 1.44 1.44 K2O 5.57 6.49 4.98 3.44 3.34 3.47 3.81 6.26 7.18 6.25 6.06 5.82 6.19 P2O5 0.01 0.02 0.01 0.05 0.05 0.06 0.05 0.15 0.14 0.2 0.15 0.16 0.21 Total 99.4 99.31 100.5 99.59 99.67 96.04 97.49 99.58 99.52 99.52 99.69 99.62 99.56 Mg# 17 12 10 36 38 39 36 65 60 61 58 64 64 Li 2.9 2.7 1.7 18.8 12.9 23.7 9.8 13.3 20.3 19.6 15.4 18.7 21.1 Be 1.23 1.31 1.09 2.65 2.25 1.73 6.03 1.82 2.12 1.95 2.14 2.04 1.75 Sc 1.6 1.1 0.9 1.9 2.3 2.2 3.8 3.7 3.6 4.2 3.2 4.1 3.6 V 30 34 32 11 10 10 14 31 37 38 28 32 33 Cr 4 2 - 8 9 13 10 1 10 1 6 13 6 Co 1.3 0.9 0.4 1.2 1.2 1.4 1.5 5.4 6.5 5.6 4.7 5.7 6 Ni 1.5 0.4 .- 0.5 0.6 0.5 0.4 2.1 4.7 1.9 3.7 8.7 4.2 Cu 0.7 7.5 1.9 1.2 0.5 .- 0.7 3.4 2.5 4.9 6.3 3.8 2.3 Zn 33 19 17 38 44 37 44 70 45 62 53 61 47 Ga 21.1 19.75 20.4 22.5 20.8 20.2 33.2 18.5 18.5 19.1 17.7 19.5 18.9 Rb 75.7 88.9 64.5 101.5 90.3 96.4 136.5 143.3 159.5 126.3 131.3 131.9 127.9 Sr 2550 1740 907 915 850 576 540 432 407 506 392 461 481 Y 7.3 9.6 11.2 5.1 5 5 5.9 11.5 14 12.3 8.8 13.9 11.4 Zr 141 235 178 146 166 154 120 139 145 130 90 109 124 Nb 6.3 4.4 5.6 4.1 4.1 3.9 7.4 9.4 12.7 9.6 10.1 11 8.6 Mo 0.09 0.14 0.09 0.11 0.48 0.08 0.12 0.42 0.14 0.37 0.21 0.22 0.03 Cd 0.04 0.03 0.06 .- .- .- 0.06 0.07 0.02 0.04 0.04 0.04 0.03 Sn 0.5 0.6 0.6 0.7 0.5 0.5 0.6 0.5 0.8 0.9 1.1 1.1 0.4 Sb 0.11 0.11 0.13 .- .- 0.09 0.21 0.53 0.2 0.14 0.27 0.18 0.11 Cs 1 0.58 0.41 1.3 0.88 1.68 1.17 3.45 3.27 2.95 2.38 2.63 2.19 Ba 2540 2410 1070 1510 1155 1285 1130 933 857 1010 829 824 881 La 18.1 10.6 4.4 18.4 17.3 17.5 8.2 39.78 38.74 36.1 41.66 34.99 33.86 Ce 35.3 22.1 13 35.7 33.1 33.9 15.6 78.06 73.42 68.2 73.46 66.09 63.61 Pr 3.75 2.36 1.73 4.08 3.64 3.73 1.75 8.14 8.36 7.84 7.11 7.61 7.16 Nd 13.5 8.7 7.1 15.4 13.3 13.5 6.2 27.29 28.79 27.36 22.75 26.19 24.89 Sm 2.34 1.64 1.35 2.59 2.25 2.13 1.18 5.5 6.2 5.78 4.59 5.82 5.4 Eu 0.67 0.53 0.46 0.59 0.49 0.52 0.47 1.18 1.17 1.29 1.01 1.18 1.18 Gd 1.55 1.22 1.29 1.63 1.36 1.37 1.07 3.43 4.09 3.75 2.77 4.01 3.51 Tb 0.23 0.19 0.19 0.18 0.16 0.16 0.15 0.49 0.56 0.51 0.38 0.52 0.46 Dy 1.17 1.12 1.3 0.75 0.7 0.74 0.86 2.71 3.12 2.79 2.11 2.9 2.51 Ho 0.22 0.24 0.3 0.14 0.12 0.13 0.16 0.5 0.61 0.52 0.4 0.57 0.48 Er 0.61 0.7 0.97 0.37 0.3 0.34 0.45 1.36 1.63 1.4 1.12 1.59 1.29 Tm 0.09 0.12 0.18 0.05 0.04 0.05 0.08 0.21 0.25 0.21 0.18 0.24 0.2 Yb 0.59 0.96 1.42 0.31 0.25 0.3 0.47 1.38 1.73 1.44 1.32 1.63 1.31 Lu 0.09 0.19 0.28 0.06 0.04 0.05 0.06 0.21 0.27 0.22 0.21 0.25 0.2 Hf 3.6 4.2 3 4.1 4.4 4 3.3 4.9 5.36 4.54 3.55 4.26 4.47 Ta 0.37 0.19 0.28 0.19 0.2 0.18 0.48 0.23 0.77 0.08 0.33 0.56 0.01 Pb 29 25.2 14.1 32.3 30 30.7 35.4 16.7 17.4 12.3 14.2 13.5 18.2 Th 1.27 0.89 0.32 3.31 2.94 2.63 1.23 16.36 19.83 14.41 15.18 17.18 18.92 U 0.75 0.61 0.34 1.14 0.47 0.64 1.01 2.18 3.55 2.29 2.75 2.09 2.14 K2O/Na2O 0.87 1.08 0.69 0.68 0.66 1.06 0.55 4.38 5.7 4.19 4.3 4.04 4.3 (La/Yb)N 22.01 7.92 2.22 42.58 49.64 41.84 12.51 20.68 16.02 18.01 22.59 15.39 18.6 (La/Sm)N 4.99 4.17 2.1 4.59 4.96 5.3 4.49 4.67 4.03 4.03 5.86 3.88 4.05 (Gd/Yb)N 2.17 1.05 0.75 4.35 4.5 3.78 1.88 2.06 1.95 2.16 1.73 2.03 2.22 Ce/Ce* 1.05 1.08 1.16 1.01 1.02 1.03 1.01 1.06 1 0.99 1.05 0.99 1 Eu/Eu* 1.08 1.15 1.07 0.88 0.86 0.93 1.28 0.83 0.71 0.84 0.87 0.75 0.83 ∑REE 78.21 50.67 33.97 80.25 73.05 74.42 36.7 170.2 169.0 157.4 159.1 153.6 146.0 TZr (℃) 750 790 762 778 789 795 744 786 775 776 754 768 774 样品号 B-0169-2 B-0169-3 B-0169-6 B-0169-7 B-0169-8 B-0169-9 JEW-1 JEW-2 ZJK-1 ZJK-5 岩性 青羊沟花岗岩 井儿洼粗安岩 张家口组流纹岩 SiO2 72.21 74.3 70 72.11 70.01 69.23 66.57 53.55 74.94 78.91 TiO2 0.26 0.2 0.36 0.19 0.38 0.44 0.54 1.63 0.28 0.15 Al2O3 14.34 13.45 15.18 14.98 15.11 15.21 13.53 18.25 15.5 11.45 Fe2O3T 1.77 1.37 2.41 1.29 2.08 2.26 4.68 7.59 1.97 0.66 MnO 0.05 0.05 0.08 0.03 0.05 0.06 0.06 0.14 0.01 0.02 MgO 0.52 0.57 1.13 0.74 1.23 0.87 2.67 1.79 0.11 0.09 CaO 0.26 0.23 0.64 0.26 0.65 0.64 2.78 6.42 0.14 0.09 Na2O 4.53 4.06 5.63 4.69 4.54 4.51 1.47 3.88 0.1 4.21 K2O 4.81 5.19 3.5 4.56 5.22 5.51 2.97 3.67 1.88 3.3 P2O5 0.06 - 0.07 0.07 0.13 0.12 0.14 0.86 0.09 0.01 Total 99.49 99.95 99.96 99.91 99.96 99.72 100.25 99.10 95.02 98.89 Mg# 41 49 52 57 58 47 57 35 12 24 Li 8.6 18.2 10.2 7.7 18.7 16.3 55.3 23.1 24.1 2.9 Be 3.19 3.7 2.23 2.07 2.37 2.43 3.71 4.37 0.92 3.93 Sc 2.5 3.3 3.5 1.3 5 5.5 10.0 13.9 4.9 2.9 V 16 8 25 13 15 19 58 85 28 4 Cr 4 6 4 4 4 5 21 1 Co 1.8 1 2.6 1.5 2 2.5 9.6 10.2 1.4 0.4 Ni 5 4.1 4.8 2.8 4 5.3 26.6 6.8 3.2 1.2 Cu 3.5 5 15.8 4.2 4.2 2.9 17.2 10.3 5.4 0.9 Zn 54 61 50 52 69 63 92.2 95.8 16 41 Ga 19.4 18.8 17.2 19.7 19.6 19.7 19.4 23.5 17.1 22.8 Rb 139.6 183.7 83.8 76.9 137.9 115 123 88 47 126 Sr 251 79 575 676 279 269 171 1135 375 68.7 Y 18.5 20.1 16.4 4.1 19.8 20.1 33.8 42.7 10.2 34.6 Zr 221 118 309 45 101 112 298 786 144 337 Nb 16.9 25.6 13.5 4.1 18.3 20.1 20.6 52.4 5 35.6 Mo 1.22 0.71 - 0.27 1.41 0.82 0.87 1.20 0.4 0.07 Cd 0.06 0.03 0.03 - 0.05 0.04 - - 0.03 0.09 Sn 2.2 3 1.6 1.1 2 2.5 3.6 4.0 0.7 0.6 Sb - - - - - - - - 0.41 0.13 Cs 1.31 1.98 0.85 1.4 1.8 1.33 8.18 1.38 2.57 0.9 Ba 489 398 959 1388 1551 1535 451 1169 620 140 La 49.95 46.59 52.54 27.68 62.99 74.46 49.89 108.78 27.7 26.2 Ce 89.11 88.92 103.3 49.1 135.6 145.7 96.4 222.8 52 67.2 Pr 10.13 10.35 11.41 5.35 15.8 15.33 10.93 25.10 5.73 6.64 Nd 33.44 35.61 38.6 18.67 51.28 50.15 39.98 93.58 20.1 22 Sm 6.49 6.9 7.3 3.79 10.21 10.51 7.38 14.68 3 5.14 Eu 0.67 0.94 1.23 0.78 1.9 1.9 1.13 3.35 0.95 0.25 Gd 4.46 4.69 4.59 1.85 6.22 6.3 7.02 12.20 2.07 4.7 Tb 0.63 0.65 0.59 0.19 0.78 0.8 1.02 1.49 0.32 0.87 Dy 3.56 3.58 3.14 0.9 4.05 4.13 6.38 8.71 1.79 5.57 Ho 0.68 0.68 0.58 0.15 0.72 0.75 1.24 1.61 0.36 1.16 Er 1.91 1.91 1.56 0.39 1.9 1.9 3.82 4.72 1 3.17 Tm 0.28 0.28 0.23 0.05 0.27 0.28 0.54 0.63 0.14 0.49 Yb 1.87 1.85 1.53 0.34 1.74 1.79 3.48 4.09 0.96 3.25 Lu 0.27 0.27 0.23 0.05 0.25 0.25 0.56 0.65 0.15 0.5 Hf 7.65 4.8 8.35 1.46 3.61 4.17 7.92 15.16 3.5 10.6 Ta 1.15 1.77 0.84 0.37 1.16 1.26 1.20 2.30 0.38 2.64 Pb 48.9 25.8 30.3 32.4 18.8 16.4 26.62 14.29 16.3 5.8 Th 15.59 13.35 11 4.13 10.96 13.07 13.44 11.56 3.8 30.4 U 2.38 1 2.11 0.67 1.57 1.44 2.65 3.40 0.47 5.49 K2O/Na2O 1.06 1.28 0.62 0.97 1.15 1.22 2.02 0.95 18.8 0.78 (La/Yb)N 19.17 18.05 24.68 58.38 25.99 29.81 10.29 19.08 20.7 5.78 (La/Sm)N 4.97 4.36 4.65 4.72 3.98 4.57 4.36 4.78 5.96 3.29 (Gd/Yb)N 1.97 2.09 2.49 4.49 2.96 2.91 1.67 2.47 1.78 1.2 Ce/Ce* 0.97 0.99 1.03 0.99 1.05 1.06 1.01 1.05 1.01 1.25 Eu/Eu* 0.38 0.51 0.65 0.9 0.73 0.71 0.48 0.77 1.17 0.16 ∑REE 203.5 203.2 226.8 109.3 293.7 314.3 229.8 502.4 116.3 147.1 TZr (℃) 819 763 843 692 744 751 861 859 871 868 注：“-”表示低于检测限; 空白表示没有测
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