Genesis of giant plagioclase phenocrysts in Cenozoic basalts from Songhuajiang River, Northeast China: Implications for the magma plumbing system of the shield-forming stage beneath Changbaishan-Tianchi Volcano
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摘要:
岩浆岩中斜长石的结构和成分可以记录其晶体的生长过程中岩浆演化的丰富信息, 从而可以灵敏反映岩浆储运系统的历史。东北地区新生代玄武岩一般多发育橄榄石和单斜辉石斑晶, 斜长石斑晶少见, 但在长白山天池造盾期(5~1Ma)玄武岩中常见有斜长石斑晶。最近我们在松花江两岸新发现一套上新世含斜长石巨斑晶(粒径为1~2cm)的玄武岩。这些沿松花江分布的斜斑玄武岩具有高Ba/Th比和K/U比的微量元素特征、EM1型的Sr-Nd-Pb同位素组成, 与长白山天池造盾期玄武岩一致。它们在主量元素上具有低镁(MgO=3.86%~4.23%)、高钛(TiO2=3.15%~4.25%)的特征, 说明其与长白山天池造盾期玄武岩中的斜斑玄武岩一样都经历了较高程度的演化。时间、空间以及地球化学特征上的紧密联系说明松花江斜斑玄武岩也是长白山天池造盾期岩浆作用的产物, 即长白山天池造盾期玄武质岩浆当时流入了松花江古河道, 向西北方向流动的距离达到了150km左右。背散射电子图像显示松花江斜斑玄武岩中斜长石巨斑晶多数具有核-边结构, 部分无环带结构, 少数具熔蚀结构。斜长石巨斑晶的化学成分变化大, 其中核-幔部主要为拉长石(An48-65), 边部为钠长石-拉长石(An4-61)。基质斜长石的化学成分也不均一, 核-幔部的组成为中长石-拉长石(An41-53), 边部为钠长石-中长石(An4-46)。多数斜长石巨斑晶的核-幔部具有细密振荡环带, An值仅呈较小幅度振荡变化, 暗示其前期生长过程中物理化学条件较为稳定, 地壳岩浆房持续受到同源岩浆的补给作用, 岩浆房持续的时间较长, 有利于斜长石巨斑晶的形成。在岩浆对流过程中晶体可被运移至温度更高的区域, 形成熔蚀结构。斜长石巨斑晶的边部An值突降以及熔蚀结构的发育, 表明斜长石巨斑晶生长后期所处的物理化学条件发生了突变, 对应于岩浆快速上升的减压过程。因此, 松花江斜斑玄武岩中的斜长石巨斑晶记录了长白山天池造盾期玄武岩在喷发前经历了较长时间的岩浆房存留过程。
Abstract:The texture and composition of plagioclase in igneous rocks can record information of magmatic evolution during the crystal growth, since it is sensitive to documenting the history of magmatic processes in magma plumbing systems. The Cenozoic basalts in Northeast China generally develop olivine and clinopyroxene phenocrysts, but plagioclase phenocrysts are rare. However, plagioclase phenocrysts are common in the shield-forming basalts (5~1Ma) of Changbaishan-Tianchi Volcano. Recently, we report a new set of Pliocene basalts on both sides of the Songhuajiang River which contain giant plagioclase phenocrysts (1~2cm in diameter). These plagioclase-phyric basalts have high Ba/Th and K/U ratios, and show EM1-type Sr-Nd-Pb isotopic composition, which is similar to those of the shield-forming basalts of Changbaishan-Tianchi Volcano. The plagioclase-phyric basalts in Songhuajiang River are characterized by low magnesium (MgO=3.86%~4.23%) and high titanium (TiO2=3.15%~4.25%) contents, indicating that the magma has undergone a high degree of evolution, which is consistent with the plagioclase-phyric basalt in the shield-forming stage of Changbaishan-Tianchi Volcano. Their temporal, spatial and geochemical relationship suggests that the plagioclase-phyric basalt of Songhuajiang River is the product of the shield-forming magmatism of Changbaishan-Tianchi Volcano, which had flowed northwestward for at least 150 kilometers along the ancient Songhuajiang River. Backscattered electron images show that most of the plagioclase phenocrysts in plagioclase-phyric basalts of Songhuajiang River have a core-rim texture, some have no zoning texture, and a few have sieve texture. The chemical composition of plagioclase phenocrysts varies greatly, in which the core-mantle area is mainly labradorite (An48-65), and the rim is albite-labradorite (An4-61). Besides, the chemical composition of the matrix plagioclase is also heterogeneous, the core-mantle component is composed of andesine-labradorite (An41-53), and the rim belongs to albite-andesine (An4-46). The core and mantle of most plagioclase phenocrysts have a fine oscillation zone, their An values only show a small amplitude oscillation, suggesting that the physical and chemical conditions of the plagioclase phenocrysts were relatively stable during the early growth process. Therefore, the magma chamber(s) should have been continuously fed by homologous magma, and lasted for a long time, which are conducive to the growth and formation of giant plagioclase phenocrysts. In the process of magmatic convection, the crystals can migrate to the higher temperature areas, forming the resorption structures. The sudden drop of An value at the rim of plagioclase phenocrysts and the development of resorption structure indicate that the physical and chemical conditions have changed during the late stage of growth of plagioclase phenocrysts, corresponding to the decompression process of rapid magma ascent. Therefore, the giant plagioclase phenocryst in plagioclase-phyric basalts of Songhuajiang River records that the shield-forming basalts in Changbaishan-Tianchi Volcano have experienced a long-term of residence process in the magma chamber(s) before eruption.
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图 1
中国东北地区(a)和长白山-松花江一带(b)新生代火山岩的分布图
Figure 1.
Distribution of Cenozoic volcanic rocks in Northeast China (a) and Changbaishan-Songhuajiang River area (b)
图 2
松花江斜斑玄武岩的手标本(a)和岩石薄片全幅面图(b，正交偏光下)
Figure 2.
Hand specimen (a) and microphotograph of rock thin section (b, under cross-polarized light) of the plagioclase-phyric basalt from Songhuajiang River
图 3
松花江斜斑玄武岩中斜长石巨斑晶的显微镜下特征
Figure 3.
Micrographs of giant plagioclase phenocryst in plagioclase-phyric basalts from Songhuajiang River
图 4
松花江斜斑玄武岩的主量元素协变图
Figure 4.
Correlations of major element compositions for plagioclase-phyric basalts from Songhuajiang River in Northeast China
图 5
松花江斜斑玄武岩球粒陨石标准化稀土元素配分图(a，标准化值据Anders and Grevesse, 1989)和原始地幔标准化微量元素蛛网图(b，标准化值据McDonough and Sun, 1995)
Figure 5.
Chondrite-normalized rare earth element patterns (a, normalization values after Anders and Grevesse, 1989) and primitive mantle-normalized trace element spider diagrams (b, normalization values after McDonough and Sun, 1995) for the plagioclase-phyric basalts from Songhuajiang River
图 6
松花江斜斑玄武岩的87Sr/86Sr-206Pb/204Pb(a)和εNd(t)-206Pb/204Pb(b)相关图
Figure 6.
87Sr/86Sr vs. 206Pb/204Pb (a) and εNd(t) vs. 206Pb/204Pb (b) for the plagioclase-phyric basalt from Songhuajiang River in Northeast China
图 7
松花江斜斑玄武岩中斜长石巨斑晶(a-c)和基质斜长石(d)的BSE图像和地球化学剖面图
Figure 7.
BSE image and geochemical profile of giant plagioclase phenocrysts (a-c) and matrix plagioclase (d) in plagioclase-phyric basalts from Songhuajiang River
图 8
松花江斜斑玄武岩中斜长石巨斑晶的阴极发光显微图像
Figure 8.
Cathodoluminescence microphotographs of giant plagioclase phenocrysts of plagioclase-phyric basalts in Songhuajiang River
图 9
松花江斜斑玄武岩中斜长石的三角分类图
Figure 9.
Ternary classification diagram of plagioclase in plagioclase-phyric basalts from Songhuajiang River
图 10
斜长石巨斑晶的Ca/Na分子比与熔体的比较
Figure 10.
Ca/Na molecular ratio of plagioclase phenocrysts compared to that of melt
图 11
松花江斜斑玄武岩的岩浆储运系统
Figure 11.
Magma plumbing system of the plagioclase-phyric basalts from Songhuajiang River
表 1
松花江斜斑玄武岩全岩的主量元素和微量元素及Sr-Nd-Pb同位素组成
Table 1.
Major element (wt%), trace element (×10-6) and Sr-Nd-Pb isotopic compositions of Songhuajiang River plagioclase-phyric basalts
样品号 19DBN-62 19DBN-63 19DBS-68 19DBS-64 19DBS-65 19DBS-61 19DBS-62 采样位置 N43°45′57.78″、E126°38′18.77″ N43°45′50.43″、E126°38′53.67″ N43°18′44.55″、E127°09′13.71″ N43°13′59.74″、E127°02′28.63″ N43°13′14.60″、E127°04′20.48″ N43°05′39.85″、E127°00′37.77″ N43°05′00.98″、E127°00′50.29″ 采样高度(m) 185.1 151.7 325.0 301.0 270.0 298.0 308.0 SiO2 51.26 51.82 50.60 50.30 50.12 50.07 50.89 TiO2 3.20 3.15 4.25 4.25 4.22 4.20 3.40 Al2O3 14.93 15.25 12.95 12.98 12.93 12.78 14.15 Fe2O3T 12.91 12.73 14.88 14.83 15.04 15.34 13.91 MnO 0.15 0.15 0.16 0.18 0.17 0.17 0.16 MgO 3.86 3.94 4.15 4.13 4.22 4.23 4.16 CaO 8.32 8.34 8.24 8.23 8.19 8.15 8.16 Na2O 3.39 3.50 3.29 3.20 3.16 3.11 3.33 K2O 1.45 1.47 1.72 1.67 1.71 1.70 1.54 P2O5 0.46 0.46 0.64 0.64 0.64 0.64 0.49 LOI -0.05 -0.48 -0.61 -0.37 -0.6 -0.57 -0.41 Total 99.88 100.33 100.27 100.04 99.80 99.82 99.78 Li 10.1 10.4 11.0 9.77 9.98 11.2 10.5 Be 1.63 1.59 1.70 1.68 1.64 1.68 1.58 Sc 23.8 23.0 26.7 25.8 25.7 26.1 23.9 V 240 231 295 289 287 290 250 Cr 39.7 37.4 8.34 7.77 7.87 7.88 34.1 Co 38.2 39.7 45.1 46.5 43.1 46.6 40.6 Ni 37.8 40.5 34.9 33.9 31.0 33.5 35.3 Cu 43.7 47.2 56.8 55.7 54.3 54.6 38.1 Zn 123 123 160 149 145 150 134 Ga 23.8 23.7 24.6 24.2 23.9 24.3 23.4 Ge 1.52 1.48 1.78 1.61 1.70 1.68 1.46 Rb 23.7 24.8 30.6 28.9 29.0 29.6 25.7 Sr 520 526 491 486 478 481 488 Y 30.0 29.5 33.9 33.8 33.2 33.7 30.9 Zr 223 222 252 250 248 252 229 Nb 21.4 20.7 23.6 23.4 23.2 23.4 21.9 Cs 0.27 0.24 0.35 0.34 0.33 0.34 0.28 Ba 497 465 519 539 521 514 489 La 22.2 21.7 25.9 26.3 25.8 25.7 22.4 Ce 47.8 48.0 59.0 60.1 59.1 58.9 49.5 Pr 6.46 6.27 7.88 8.00 7.79 7.77 6.30 Nd 31.2 30.3 37.8 38.3 37.7 37.4 31.7 Sm 7.98 7.67 9.48 9.64 9.50 9.48 8.11 Eu 2.67 2.60 3.13 3.14 3.09 3.08 2.67 Gd 7.62 7.45 8.89 9.04 8.81 8.82 7.63 Tb 1.11 1.08 1.29 1.30 1.28 1.28 1.13 Dy 6.18 6.00 7.03 7.12 6.99 6.99 6.26 Ho 1.11 1.09 1.25 1.27 1.23 1.24 1.14 Er 2.87 2.82 3.14 3.19 3.14 3.15 2.92 Tm 0.39 0.37 0.41 0.41 0.40 0.41 0.39 Yb 2.29 2.25 2.41 2.45 2.41 2.41 2.32 Lu 0.32 0.32 0.34 0.34 0.33 0.34 0.32 Hf 5.50 5.45 6.22 6.22 6.16 6.16 5.56 Ta 1.31 1.27 1.43 1.45 1.42 1.42 1.32 Pb 4.04 3.95 4.61 4.47 4.54 4.31 3.85 Th 2.20 2.14 2.56 2.57 2.52 2.56 2.27 U 0.42 0.44 0.50 0.51 0.50 0.57 0.49 87Sr/86Sr 0.704985 0.704911 0.705098 0.705112 0.705100 0.705085 0.704918 2SE 0.000005 0.000008 0.000006 0.000013 0.000006 0.000008 0.000009 143Nd/144Nd 0.512611 0.512614 0.512589 0.512580 0.512594 0.512583 0.512603 2SE 0.000005 0.000008 0.000014 0.000007 0.000008 0.000005 0.000005 206Pb/204Pb 17.310 17.309 17.264 17.263 17.265 17.266 17.312 2SE 0.001 0.001 0.001 0.001 0.001 0.001 0.001 207Pb/204Pb 15.531 15.531 15.536 15.534 15.535 15.536 15.531 2SE 0.001 0.001 0.001 0.001 0.001 0.001 0.001 208Pb/204Pb 37.514 37.515 37.498 37.4960 37.499 37.500 37.515 2SE 0.002 0.002 0.002 0.002 0.002 0.002 0.002 注：LOI表示烧矢量. Fe2O3T表示全铁以Fe2O3的形式表达 
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